A simple topological identification method for highly (3,12)-connected 3D MOFs showing anion exchange and luminescent properties

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Abstract

Reaction of a semi-rigid tripodal ligand 1,1’,1’-(2,4,6-trimethylbenzene-1,3,5-triyl)tris(methylene)tripyridinium-4-olate) (TTP) with Ln3+ (Ln = Eu, Gd) afforded rare (3,12)-connected metal-organic frameworks (MOFs). A topological simplification of such highly connected 3D MOFs on the basis of 2D CdI2 (3,6)-nets is proposed. The luminescent and anion exchange properties of the compounds were determined.

Original languageEnglish
Pages (from-to)4234-4236
Number of pages3
JournalChemical Communications
Volume47
Issue number14
DOIs
StatePublished - 22 Mar 2011
Externally publishedYes

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