A robust thorium-organic framework as a bifunctional platform for iodine adsorption and Cr(vi) sensitization

Yiran Fu; Xue Wang; Yu Ju; Zhaofa Zheng; Jie Jian; Zi Jian Li; Chan Jin; Jian Qiang Wang; Jian Lin

doi:10.1039/d2dt03623a

A robust thorium-organic framework as a bifunctional platform for iodine adsorption and Cr(vi) sensitization

Yiran Fu
, Xue Wang
, Yu Ju
, Zhaofa Zheng
, Jie Jian
, Zi Jian Li
, Chan Jin
, Jian Qiang Wang
, Jian Lin

School of Energy and Power Engineering

Research output: Contribution to journal › Article › peer-review

10 Scopus citations

Abstract

Simple synthetic modulation based on thorium nitrate and tris((4-carboxyl)phenylduryl)amine (H₃TCBPA) gives rise to a new thorium-based metal-organic framework, Th-TCBPA, which features excellent hydrolytic and thermal stabilities. Incorporating electron-rich TCBPA³⁻ linkers not only endows Th-TCBPA with high adsorption capacity toward radioiodine vapor, but also makes it a luminescence sensor for the highly sensitive and selective detection of Cr(vi) anions.

Original language	English
Pages (from-to)	1177-1181
Number of pages	5
Journal	Dalton Transactions
Volume	52
Issue number	5
DOIs	https://doi.org/10.1039/d2dt03623a
State	Published - 6 Jan 2023

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title = "A robust thorium-organic framework as a bifunctional platform for iodine adsorption and Cr(vi) sensitization",

abstract = "Simple synthetic modulation based on thorium nitrate and tris((4-carboxyl)phenylduryl)amine (H3TCBPA) gives rise to a new thorium-based metal-organic framework, Th-TCBPA, which features excellent hydrolytic and thermal stabilities. Incorporating electron-rich TCBPA3− linkers not only endows Th-TCBPA with high adsorption capacity toward radioiodine vapor, but also makes it a luminescence sensor for the highly sensitive and selective detection of Cr(vi) anions.",

author = "Yiran Fu and Xue Wang and Yu Ju and Zhaofa Zheng and Jie Jian and Li, \{Zi Jian\} and Chan Jin and Wang, \{Jian Qiang\} and Jian Lin",

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doi = "10.1039/d2dt03623a",

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T1 - A robust thorium-organic framework as a bifunctional platform for iodine adsorption and Cr(vi) sensitization

AU - Fu, Yiran

AU - Wang, Xue

AU - Ju, Yu

AU - Zheng, Zhaofa

AU - Jian, Jie

AU - Li, Zi Jian

AU - Jin, Chan

AU - Wang, Jian Qiang

AU - Lin, Jian

PY - 2023/1/6

Y1 - 2023/1/6

N2 - Simple synthetic modulation based on thorium nitrate and tris((4-carboxyl)phenylduryl)amine (H3TCBPA) gives rise to a new thorium-based metal-organic framework, Th-TCBPA, which features excellent hydrolytic and thermal stabilities. Incorporating electron-rich TCBPA3− linkers not only endows Th-TCBPA with high adsorption capacity toward radioiodine vapor, but also makes it a luminescence sensor for the highly sensitive and selective detection of Cr(vi) anions.

AB - Simple synthetic modulation based on thorium nitrate and tris((4-carboxyl)phenylduryl)amine (H3TCBPA) gives rise to a new thorium-based metal-organic framework, Th-TCBPA, which features excellent hydrolytic and thermal stabilities. Incorporating electron-rich TCBPA3− linkers not only endows Th-TCBPA with high adsorption capacity toward radioiodine vapor, but also makes it a luminescence sensor for the highly sensitive and selective detection of Cr(vi) anions.

UR - https://www.scopus.com/pages/publications/85147317832

U2 - 10.1039/d2dt03623a

DO - 10.1039/d2dt03623a

M3 - 文章

C2 - 36648495

AN - SCOPUS:85147317832

SN - 1477-9226

VL - 52

SP - 1177

EP - 1181

JO - Dalton Transactions

JF - Dalton Transactions

IS - 5

ER -

A robust thorium-organic framework as a bifunctional platform for iodine adsorption and Cr(vi) sensitization

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