A novel 3D porous cadmium(II) MOF based on conjugated ligand with potential application for sensing small linear conjugated molecule

Zhao Jin; Huanyu Zhao; Dongjiang Yang; Xiangdong Yao; Guangshan Zhu

doi:10.1016/j.inoche.2012.09.011

A novel 3D porous cadmium(II) MOF based on conjugated ligand with potential application for sensing small linear conjugated molecule

Zhao Jin
, Huanyu Zhao
, Dongjiang Yang
, Xiangdong Yao
, Guangshan Zhu

School of Energy and Power Engineering

Research output: Contribution to journal › Article › peer-review

17 Scopus citations

Abstract

A novel 3D porous MOF [Cd ₃(ABTA) ₂(DMF) (H ₂O) ₂] (1) (ABTA = 3, 4′, 5-azobenzenetricarboxylate) has been successfully synthesized by solvothermal reaction of Cd(NO ₃) ₂4H ₂O with ABTA. Single-crystal X-ray diffraction result reveals that complex 1 possesses a complicated 3D open framework with two intercrossed 1D channels along [200] and [11-1]. The photoluminescence experimental results of the complex in different solvents indicate that complex 1 has potential application in recognizing small linear conjugated molecule.

Original language	English
Pages (from-to)	74-78
Number of pages	5
Journal	Inorganic Chemistry Communications
Volume	25
DOIs	https://doi.org/10.1016/j.inoche.2012.09.011
State	Published - Nov 2012

Keywords

(3,3,6)-connected topology
3,4′, 5-azobenzenetricarboxylate
3D open framework
Luminescent properties
Sensor

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10.1016/j.inoche.2012.09.011

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title = "A novel 3D porous cadmium(II) MOF based on conjugated ligand with potential application for sensing small linear conjugated molecule",

abstract = "A novel 3D porous MOF [Cd 3(ABTA) 2(DMF) (H 2O) 2] (1) (ABTA = 3, 4′, 5-azobenzenetricarboxylate) has been successfully synthesized by solvothermal reaction of Cd(NO 3) 24H 2O with ABTA. Single-crystal X-ray diffraction result reveals that complex 1 possesses a complicated 3D open framework with two intercrossed 1D channels along [200] and [11-1]. The photoluminescence experimental results of the complex in different solvents indicate that complex 1 has potential application in recognizing small linear conjugated molecule.",

keywords = "(3,3,6)-connected topology, 3,4′, 5-azobenzenetricarboxylate, 3D open framework, Luminescent properties, Sensor",

author = "Zhao Jin and Huanyu Zhao and Dongjiang Yang and Xiangdong Yao and Guangshan Zhu",

year = "2012",

month = nov,

doi = "10.1016/j.inoche.2012.09.011",

language = "英语",

volume = "25",

pages = "74--78",

journal = "Inorganic Chemistry Communications",

issn = "1387-7003",

publisher = "Elsevier B.V.",

}

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T1 - A novel 3D porous cadmium(II) MOF based on conjugated ligand with potential application for sensing small linear conjugated molecule

AU - Jin, Zhao

AU - Zhao, Huanyu

AU - Yang, Dongjiang

AU - Yao, Xiangdong

AU - Zhu, Guangshan

PY - 2012/11

Y1 - 2012/11

N2 - A novel 3D porous MOF [Cd 3(ABTA) 2(DMF) (H 2O) 2] (1) (ABTA = 3, 4′, 5-azobenzenetricarboxylate) has been successfully synthesized by solvothermal reaction of Cd(NO 3) 24H 2O with ABTA. Single-crystal X-ray diffraction result reveals that complex 1 possesses a complicated 3D open framework with two intercrossed 1D channels along [200] and [11-1]. The photoluminescence experimental results of the complex in different solvents indicate that complex 1 has potential application in recognizing small linear conjugated molecule.

AB - A novel 3D porous MOF [Cd 3(ABTA) 2(DMF) (H 2O) 2] (1) (ABTA = 3, 4′, 5-azobenzenetricarboxylate) has been successfully synthesized by solvothermal reaction of Cd(NO 3) 24H 2O with ABTA. Single-crystal X-ray diffraction result reveals that complex 1 possesses a complicated 3D open framework with two intercrossed 1D channels along [200] and [11-1]. The photoluminescence experimental results of the complex in different solvents indicate that complex 1 has potential application in recognizing small linear conjugated molecule.

KW - (3,3,6)-connected topology

KW - 3,4′, 5-azobenzenetricarboxylate

KW - 3D open framework

KW - Luminescent properties

KW - Sensor

UR - https://www.scopus.com/pages/publications/84867493006

U2 - 10.1016/j.inoche.2012.09.011

DO - 10.1016/j.inoche.2012.09.011

M3 - 文章

AN - SCOPUS:84867493006

SN - 1387-7003

VL - 25

SP - 74

EP - 78

JO - Inorganic Chemistry Communications

JF - Inorganic Chemistry Communications

ER -

A novel 3D porous cadmium(II) MOF based on conjugated ligand with potential application for sensing small linear conjugated molecule

Abstract

Keywords

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