A novel 3D open framework constructed by [Co15(PMIDA) 6(H2O)12] clusters and BTC ligands

Xiao Rui Wang; Qing Xiang Jia; Zhi Hong Liu

doi:10.1016/j.inoche.2011.11.002

A novel 3D open framework constructed by [Co₁₅(PMIDA) ₆(H₂O)₁₂] clusters and BTC ligands

Xiao Rui Wang
, Qing Xiang Jia
, Zhi Hong Liu

School of Chemistry

Shaanxi Normal University

Research output: Contribution to journal › Article › peer-review

9 Scopus citations

Abstract

A new cobalt coordination polymer based on N-(Phosphonomethyl)imino- diacetic acid (H₄PMIDA) and 1,3,5-benzenetricarboxylate acid (H ₃BTC) ligands, [Co₁₅(PMIDA)₆(BTC) ₂(H₂O)₁₂]•6H₂O, has been synthesized under hydrothermal conditions, and characterized by elemental analysis, FT-IR spectroscopy, thermal analysis, and single crystal X-ray diffraction. The structure of the complex features a cubic 3D open framework constructed by [Co₁₅(PMIDA)₆(H₂O)₁₂] cluster and BTC ligand. The magnetic properties of this compound were also investigated.

Original language	English
Pages (from-to)	281-284
Number of pages	4
Journal	Inorganic Chemistry Communications
Volume	15
DOIs	https://doi.org/10.1016/j.inoche.2011.11.002
State	Published - Jan 2012

Keywords

Cobalt coordination polymer
Crystal structure
Hydrothermal synthesis
Magnetic properties
Mixture ligands

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10.1016/j.inoche.2011.11.002

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title = "A novel 3D open framework constructed by [Co15(PMIDA) 6(H2O)12] clusters and BTC ligands",

abstract = "A new cobalt coordination polymer based on N-(Phosphonomethyl)imino- diacetic acid (H4PMIDA) and 1,3,5-benzenetricarboxylate acid (H 3BTC) ligands, [Co15(PMIDA)6(BTC) 2(H2O)12]•6H2O, has been synthesized under hydrothermal conditions, and characterized by elemental analysis, FT-IR spectroscopy, thermal analysis, and single crystal X-ray diffraction. The structure of the complex features a cubic 3D open framework constructed by [Co15(PMIDA)6(H2O)12] cluster and BTC ligand. The magnetic properties of this compound were also investigated.",

keywords = "Cobalt coordination polymer, Crystal structure, Hydrothermal synthesis, Magnetic properties, Mixture ligands",

author = "Wang, \{Xiao Rui\} and Jia, \{Qing Xiang\} and Liu, \{Zhi Hong\}",

year = "2012",

month = jan,

doi = "10.1016/j.inoche.2011.11.002",

language = "英语",

volume = "15",

pages = "281--284",

journal = "Inorganic Chemistry Communications",

issn = "1387-7003",

publisher = "Elsevier B.V.",

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TY - JOUR

T1 - A novel 3D open framework constructed by [Co15(PMIDA) 6(H2O)12] clusters and BTC ligands

AU - Wang, Xiao Rui

AU - Jia, Qing Xiang

AU - Liu, Zhi Hong

PY - 2012/1

Y1 - 2012/1

N2 - A new cobalt coordination polymer based on N-(Phosphonomethyl)imino- diacetic acid (H4PMIDA) and 1,3,5-benzenetricarboxylate acid (H 3BTC) ligands, [Co15(PMIDA)6(BTC) 2(H2O)12]•6H2O, has been synthesized under hydrothermal conditions, and characterized by elemental analysis, FT-IR spectroscopy, thermal analysis, and single crystal X-ray diffraction. The structure of the complex features a cubic 3D open framework constructed by [Co15(PMIDA)6(H2O)12] cluster and BTC ligand. The magnetic properties of this compound were also investigated.

AB - A new cobalt coordination polymer based on N-(Phosphonomethyl)imino- diacetic acid (H4PMIDA) and 1,3,5-benzenetricarboxylate acid (H 3BTC) ligands, [Co15(PMIDA)6(BTC) 2(H2O)12]•6H2O, has been synthesized under hydrothermal conditions, and characterized by elemental analysis, FT-IR spectroscopy, thermal analysis, and single crystal X-ray diffraction. The structure of the complex features a cubic 3D open framework constructed by [Co15(PMIDA)6(H2O)12] cluster and BTC ligand. The magnetic properties of this compound were also investigated.

KW - Cobalt coordination polymer

KW - Crystal structure

KW - Hydrothermal synthesis

KW - Magnetic properties

KW - Mixture ligands

UR - https://www.scopus.com/pages/publications/84655166543

U2 - 10.1016/j.inoche.2011.11.002

DO - 10.1016/j.inoche.2011.11.002

M3 - 文章

AN - SCOPUS:84655166543

SN - 1387-7003

VL - 15

SP - 281

EP - 284

JO - Inorganic Chemistry Communications

JF - Inorganic Chemistry Communications

ER -

A novel 3D open framework constructed by [Co₁₅(PMIDA) ₆(H₂O)₁₂] clusters and BTC ligands

Abstract

Keywords

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