A C,S bonded quasi-two-coordinate chromium(ii) complex showing field-induced slow magnetic relaxation behaviour

Qian Cheng Luo; Ning Ge; Yuan Qi Zhai; Teng Bo Wang; Lin Sun; Qi Sun; Fanni Li; Zhongwen Ouyang; Zhen Xing Wang; Yan Zhen Zheng

doi:10.1039/d2dt01131j

A C,S bonded quasi-two-coordinate chromium(ii) complex showing field-induced slow magnetic relaxation behaviour

Qian Cheng Luo
, Ning Ge
, Yuan Qi Zhai
, Teng Bo Wang
, Lin Sun
, Qi Sun
, Fanni Li
, Zhongwen Ouyang
, Zhen Xing Wang
, Yan Zhen Zheng

School of Materials Science and Engineering

Xi'an Jiaotong University
Henan University
The First Affiliated Hospital of Xi’an Jiaotong University
Huazhong University of Science and Technology

Research output: Contribution to journal › Article › peer-review

9 Scopus citations

Abstract

A C,S bonded quasi-two-coordinate Cr(ii) complex, Cr(SAr*)₂ (HSAr* = HSC₆H₃-2,6(C₆H₂-2,4,6-Prⁱ₃)₂), has been synthesized according to literature precedent. Magnetic measurements, high-frequency/field electron paramagnetic resonance (HF-EPR) experiments and ab initio calculation studies show that the field-induced slow magnetic relaxation behaviour is caused by relatively weak axial magnetic anisotropy.

Original language	English
Pages (from-to)	9218-9222
Number of pages	5
Journal	Dalton Transactions
Volume	51
Issue number	24
DOIs	https://doi.org/10.1039/d2dt01131j
State	Published - 26 Apr 2022

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title = "A C,S bonded quasi-two-coordinate chromium(ii) complex showing field-induced slow magnetic relaxation behaviour",

abstract = "A C,S bonded quasi-two-coordinate Cr(ii) complex, Cr(SAr*)2 (HSAr* = HSC6H3-2,6(C6H2-2,4,6-Pri3)2), has been synthesized according to literature precedent. Magnetic measurements, high-frequency/field electron paramagnetic resonance (HF-EPR) experiments and ab initio calculation studies show that the field-induced slow magnetic relaxation behaviour is caused by relatively weak axial magnetic anisotropy.",

author = "Luo, \{Qian Cheng\} and Ning Ge and Zhai, \{Yuan Qi\} and Wang, \{Teng Bo\} and Lin Sun and Qi Sun and Fanni Li and Zhongwen Ouyang and Wang, \{Zhen Xing\} and Zheng, \{Yan Zhen\}",

note = "Publisher Copyright: {\textcopyright} 2022 The Royal Society of Chemistry.",

year = "2022",

month = apr,

day = "26",

doi = "10.1039/d2dt01131j",

language = "英语",

volume = "51",

pages = "9218--9222",

journal = "Dalton Transactions",

issn = "1477-9226",

publisher = "Royal Society of Chemistry",

number = "24",

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TY - JOUR

T1 - A C,S bonded quasi-two-coordinate chromium(ii) complex showing field-induced slow magnetic relaxation behaviour

AU - Luo, Qian Cheng

AU - Ge, Ning

AU - Zhai, Yuan Qi

AU - Wang, Teng Bo

AU - Sun, Lin

AU - Sun, Qi

AU - Li, Fanni

AU - Ouyang, Zhongwen

AU - Wang, Zhen Xing

AU - Zheng, Yan Zhen

PY - 2022/4/26

Y1 - 2022/4/26

N2 - A C,S bonded quasi-two-coordinate Cr(ii) complex, Cr(SAr*)2 (HSAr* = HSC6H3-2,6(C6H2-2,4,6-Pri3)2), has been synthesized according to literature precedent. Magnetic measurements, high-frequency/field electron paramagnetic resonance (HF-EPR) experiments and ab initio calculation studies show that the field-induced slow magnetic relaxation behaviour is caused by relatively weak axial magnetic anisotropy.

AB - A C,S bonded quasi-two-coordinate Cr(ii) complex, Cr(SAr*)2 (HSAr* = HSC6H3-2,6(C6H2-2,4,6-Pri3)2), has been synthesized according to literature precedent. Magnetic measurements, high-frequency/field electron paramagnetic resonance (HF-EPR) experiments and ab initio calculation studies show that the field-induced slow magnetic relaxation behaviour is caused by relatively weak axial magnetic anisotropy.

UR - https://www.scopus.com/pages/publications/85131967013

U2 - 10.1039/d2dt01131j

DO - 10.1039/d2dt01131j

M3 - 文章

C2 - 35670316

AN - SCOPUS:85131967013

SN - 1477-9226

VL - 51

SP - 9218

EP - 9222

JO - Dalton Transactions

JF - Dalton Transactions

IS - 24

ER -

A C,S bonded quasi-two-coordinate chromium(ii) complex showing field-induced slow magnetic relaxation behaviour

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