A budget analysis of the formation of haze in Beijing

During recent winters, hazes often occurred in Beijing, causing major environmental problems. To understand the causes of this "Beijing Haze", a haze episode (from Oct. 21 to Oct. 31, 2013) in Beijing was analyzed. During the episode, the daily mean concentration of fine particulate matter (PM_2.5) reached a peak value of 270μg/m³ on Oct. 28, 2013, and rapidly decreased to 50μg/m³ the next day (Oct. 29, 2013). This strong variability provided a good opportunity to study the causes of a "Beijing Haze". Two numerical models were applied for this study. The first model is a chemical/dynamical regional model (WRF-Chem). This model is mainly used to study the effects that weather conditions have on PM_2.5 concentrations in the Beijing region. The results show that the presence of high air pressure in northwest Beijing (NW-High) generally produced strong northwest winds with clean upwind air. As a result, the NW-High played an important role in cleaning Beijing's PM. However, the NW-High's cleaning effect did not occur in every situation. When there was low air pressure in southeast Beijing (SE-Low) accompanied by an NW-High, an air convergent zone appeared in Beijing. The pollutants became sandwiched, producing high PM_2.5 concentrations in the Beijing region. The second model used in this study is a box model, which is applied to estimate some crucial parameters associated with the budget of PM_2.5 in the Beijing region. Under calm winds, the calculations show that continuous local emissions rapidly accumulate pollutants. The PM_2.5 concentrations reached 150μg/m³ and 250μg/m³ within one (1) day and two (2) days, respectively. Without horizontal dilution, this estimate can be considered as an upper time limit (the fastest time) for the occurrences of haze events in the Beijing region. The wind speed (WS_b) is calculated for the balance between the continuous emissions and atmospheric clean processes. The results show that the WS_b is strongly dependent on the planetary boundary layer (PBL) height and the wind direction. Under SE-Low weather conditions, the WS_b is 2m/s with a higher PBL height (700m). However, under lower PBL heights, the WS_b rapidly increases, reaching 4.5m/s and 7.0m/s with PBL heights of 300m and 200m, respectively. In contrast, under NW-High weather conditions, the WS_b reduces to 2.5m/s and 4.0m/s. These results suggest that when the prevailing wind in Beijing is a northwest wind (with wind speeds of >4m/s), particulate matter (PM) begins to decrease.