不同空气分级模式下氨煤掺烧数值模拟

Translated title of the contribution: Modeling co-firing ammonia with coal in different air staging modes
  • Tao Niu
  • , Wenzhen Zhang
  • , Shuzhou Wei
  • , Chaoqun Zhang
  • , Ming Li
  • , Wei Chu
  • , Ping Liu
  • , Lun Ma
  • , Xuebin Wang

Research output: Contribution to journalArticlepeer-review

6 Scopus citations

Abstract

Recently, ammonia has garnered significant attentionaround the world as an effective zero-carbon fuel and hydrogen storage medium. To reduce carbon emissions in coal - fired power plants, the use of zero - carbon fuel blends shows great promise. Investigates the combustion behavior of ammonia coal co-firing under the deep-air staging mode. Specifically, the temperature field, component concentration field, and nitrogen oxide emission in the furnace at varying α coefficient conditions are investigated, while maintaining the total excess air coefficient at 1.2. The study analyzes four cases with α coefficients equal to 0.696, 0.840, 0.912, and 0.996 respectively. The temperature field reveals that as the α coefficient decreases, the ignition position of the first stage of pulverized coal combustion advances. However, the length of the high-temperature flame formed is shortened, and the temperature near the ammonia injection port is notably lower. When α = 0.696, the pulverized coal flame and ammonia combustion flame are distinctly separate, but as α improves, the boundary between the two gradually becomes blurred. Decreasing the α coefficient forms a longer reduction zone upstream of ammonia fuel injection, leading to a lower oxygen concentration of ammonia fuel at the moment of injection, hence reducing the probability of ammonia oxidation path. However, as the α decreases, there is a corresponding decrease in burnout in the furnace,which includes CO emissions concentration, fly ash carbon content, and ammonia escape. However, the influence is very limited in this simulation. Statistical analysis of NOx concentration in the furnace showed that NOx emissions significantly decreased as α decreased. Furthermore, the highest H2 concentration in the furnace reached 2% under α = 0.696, led to a significant enhancement of ammonia decomposition reaction. Since the consumption reaction of ammonia depends on three global reactions, improved decomposition reaction can reduce the direct participation in oxidation for ammonia. Increased H2 production also enhances the possibility of nitrogen oxide reduction, leading to further decreases in NOx emissions. Ultimately, utilizing the air depth classification method can optimize the temperature and oxygen concentration within the ammonia combustion area, contributing to achieve the low NOx emissions in the furnace.

Translated title of the contributionModeling co-firing ammonia with coal in different air staging modes
Original languageChinese (Traditional)
Pages (from-to)145-151
Number of pages7
JournalClean Coal Technology
Volume29
Issue number9
DOIs
StatePublished - Oct 2023

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